Get The Endpoint
You need the instance endpoint if you want to execute direct REST calls.
Go to Settings > Customizations > Developer Resources and copy the Service Root URL and use it as [Organization URI] in the examples provided by the documentation.

Source: Query data using the Web API
Basic Retrieve Multiple
Use the method Xrm.WebApi.retrieveMultipleRecords to retrieve multiple records.
Xrm.WebApi.retrieveMultipleRecords("account", "?$select=name&$top=3").then( function success(result) { for (var i = 0; i < result.entities.length; i++) { console.log(result.entities[i]); } // perform additional operations on retrieved records }, function (error) { console.log(error.message); // handle error conditions } );